Champions League Preview: EXCLUSIVE Yamal Boost, Matchweek 3 Fixtures, Winner Odds and Top Scorers

The UEFA Champions League returns this week with Barcelona and PSG joint-favourites at 11/2, while Arsenal, Liverpool, and Manchester City headline another stacked matchweek. Fans can also enter bet365’s Ticket Giveaway for the chance to win tickets to upcoming fixtures.
Champions League Preview: EXCLUSIVE Yamal Boost, Matchweek 3 Fixtures, Winner Odds and Top Scorers

Vyacheslav Evdokimov, CC BY-SA 3.0 GFDL, via Wikimedia Commons

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  • Lamine Yamal has been boosted with bet365 to score 2 or more against Olympiakos
  • Barcelona and PSG are joint-favourites at 11/2, ahead of Arsenal (6/1) and Liverpool (13/2).
  • Kylian Mbappé (2/1) remains Golden Boot favourite ahead of Harry Kane (9/2) and Erling Haaland (11/2).
  • English clubs dominate the outright market, with four of the top eight teams hailing from the Premier League.

Bet365 boost Lamine Yamal to score 2 or more against Olympiacos

OLBG's exclusive boost with bet365 for this week's Champions League fixtures is for Lamine Yamal to score two or more for Barcelona vs Olympiacos.

Barca's starboy is looking to help Barcelona towards the top 8 of the Champions League table this midweek and he has been boosted for goals.

Get OLBG's Exclusive Boosted Odds Here

BOOST!

Odds correct as of 15:30 Monday 20th October:

The UEFA Champions League league stage continues this week with a packed slate of fixtures on Tuesday 21st and Wednesday 22nd October 2025, as teams fight to move up the league table.

There’s plenty to play for both on the pitch and in the markets with English clubs dominating the outright betting and a tight race in the Golden Boot stakes.

Meanwhile, bet365 are giving fans the chance to win free tickets to Champions League games as part of their ongoing giveaway.

Champions League 25/26 – Outright Winner Odds

Champions League Winner 25/26OddsImplied Probability
Barcelona11/2
15.4%
PSG11/215.4%
Arsenal6/1
14.3%
Liverpool13/2
13.3%
Real Madrid9/1
10.0%
Bayern Munich9/1
10.0%
Manchester City10/1
9.1%
Chelsea16/1
5.9%

Top Goalscorer Betting

Champions League Top Goalscorer 25/26Odds
Kylian Mbappé (PSG)2/1
Harry Kane (Bayern Munich)9/2
Erling Haaland (Man City)11/2
Mohamed Salah (Liverpool)16/1
Robert Lewandowski (Barcelona)20/1

Mbappé (2/1) remains the front-runner after a string of dominant performances, but Harry Kane (9/2) is pushing hard and Erling Haaland (11/2) remains a threat, especially if City’s form picks up.

Nationality of Winning Team

Nationality of Winning Team
Odds
England21/20
Spain12/5
France5/1
Germany11/2
Italy15/2
Any Other Nation14/1

With four Premier League clubs among the top eight contenders, it's no surprise that England leads the nationality betting market.

Fixtures – Matchweek 3

Tuesday, 21 October

  • 17:45: Barcelona vs Olympiakos
  • 17:45: Kairat vs Pafos
  • 20:00: Arsenal vs Atletico Madrid
  • 20:00: Bayer Leverkusen vs PSG
  • 20:00: Copenhagen vs Borussia Dortmund
  • 20:00: Newcastle United vs Benfica
  • 20:00: PSV vs Napoli
  • 20:00: Union Saint-Gilloise vs Inter Milan
  • 20:00: Villarreal vs Manchester City

Wednesday, 22 October

  • 17:45: Athletic Club vs Qarabağ
  • 17:45: Galatasaray vs Bodø/Glimt
  • 20:00: Atalanta vs Slavia Prague
  • 20:00: Bayern Munich vs Club Brugge
  • 20:00: Chelsea vs Ajax
  • 20:00: Eintracht Frankfurt vs Liverpool
  • 20:00: Monaco vs Tottenham Hotspur
  • 20:00: Real Madrid vs Juventus
  • 20:00: Sporting CP vs Marseille

bet365 Champions League Ticket Giveaway

bet365 are giving fans the chance to win Champions League tickets with their Matchweek 5 Ticket Giveaway.

Here’s how to enter:

  1. Log in or create a bet365 account
  2. Head to the ticket giveaway page
  3. Select your chosen fixture
  4. Click Enter before the deadline (23 October 2025)

Current Giveaway:

  • Matchweek 5: 25–26 November 2025
  • Entry Window: 10–23 October 2025

Full T&Cs apply on bet365’s promotions page.

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